I managed to figure this out myself.
Settings below works for my situation.
DISCOURSE_SMTP_ADDRESS: smtp.myquickid.synology.me
DISCOURSE_SMTP_PORT: 25
#DISCOURSE_SMTP_USER_NAME: admin@mydomain.com
#DISCOURSE_SMTP_PASSWORD: "plainpass"
DISCOURSE_SMTP_ENABLE_START_TLS: false # (optional, default true)
#DISCOURSE_SMTP_OPENSSL_VERIFY_MODE: none
#DISCOURSE_SMTP_AUTHENTICATION: none
DISCOURSE_SMTP_OPENSSL_VERIFY_MODE: none
Ignoring user name and password is weird though.