For the record, the docs make this pretty confusing and this is not the first time I have found myself googling this exact issue trying to find the solution.
Docs currently have:
SendGrid — 40k emails on a 30 day trial
SMTP server address? smtp.sendgrid.net
SMTP user name? apikey
SMTP password? [SendGrid API Key]
EDIT: What I think is confusing people is that they (like me) think apikey means put your apikey here but infact it should be left alone!