I can't seem to be able to locate when this notification is configured from?

Hello and welcome @Stephane_Gonthier :slight_smile:

That notification is for moderators for when there have been items in the Review Queue for a certain amount of time. There are a couple of settings for the different versions so you can choose what the time threshold is for each - notify about reviewable item after (flags) and notify about queued posts after (things that need approval).

But neither would notify you about topics that have not had a reply yet. I think you would need to run a data explorer query to get those.

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